8.3 Concentration of Solution
Concentration of Solutions can be expressed in different ways as follows :
i)Weight percentage of solute is the weight of solute (´ 100), divided by the total weight of the solution.
i.e. 10% w/w of NaCl means 10 gms of NaCl is present in a 100 g of solution.
ii) The molarity, M, of a solution is the
number of moles of solute per kg of solvent.
20 M of sodium chloride solution means 20 moles (20 ´ 55.5 gms) of sodium chloride dissolved in a solvent to get one liter of solution.
iii) The molality, m, of a solution is the number of moles of solute per kg of solution.
12 m of sodium chloride solution means 12 moles (12 ´ 55.5 gms) of sodium chloride dissolved in a solvent to get 1 kg of solution.
iv) The normality, N, of a solution is the number
of gram equivalent weight of solute per liter of solution.
5 N of sulphuric acid solution means ( 5 ´ 49 gms ) ( \ eq. wt = mol.wt / no.of equivalents = 98/2 = 49 ) of sulphuric acid dissolved in solvent to get one liter of solution.
v) The mole fraction, X, is the ratio of the number of moles of solute ( or solvent ) to the total number of moles of all components in a solution.
In a 10% HCl solution in H2O
At a glance the concentration of solutions:
No. |
Name |
Symbol |
Explanation |
1 |
Weight percentage |
% w/w |
Weight of solute in percentage in 100 gm of solution. |
2 |
Molarity |
M |
Number of moles of solute per liter of solution. |
3 |
Molality |
m |
Number of moles of solute per kg of solution. |
4 |
Normality |
N |
Number of gram equivalent weights of solute per liter of solution. |
5 |
Mole fraction |
X |
Ratio of the number of moles of solute (or solvent) to the total number of moles of all components in a solution. |
|